1 00:00:01,260 --> 00:00:07,259 Hello tiny scientists! In this video you're going to learn how to make binary compounds which are 2 00:00:07,259 --> 00:00:12,300 compounds of two elements from the periodic table. I need you to remember the octet rule 3 00:00:12,300 --> 00:00:17,980 because we're going to use it to explain how atoms combine with others making compounds. 4 00:00:18,699 --> 00:00:27,579 Finally you will learn how to write the formula of a compound in the right order. The octet rule 5 00:00:27,579 --> 00:00:33,979 is a very simple way to explain how atoms combine. Basically it says that every atom from the predict 6 00:00:33,979 --> 00:00:39,340 table wants to have eight electrons in the last shell becoming like the closest noble gas. 7 00:00:40,060 --> 00:00:47,979 Notice that all noble gases except helium which is too small all noble gases have eight electrons 8 00:00:47,979 --> 00:00:55,979 in their last shell. There are some exceptions. Let's apply the octet rule to some elements to 9 00:00:55,979 --> 00:01:02,380 see if we can predict the behavior of atoms when they combine for example chlorine which is the 10 00:01:02,939 --> 00:01:12,420 closest let's apply the octet rule to some elements to see if we can predict the behavior 11 00:01:12,420 --> 00:01:19,540 of atoms when they combine for example chlorine which is the previous element to argon has 12 00:01:20,340 --> 00:01:26,579 seven electrons in the last shell and eight electrons in the previous one so if chlorine 13 00:01:26,579 --> 00:01:33,299 wants to become a noble gas if he wants to have eight electrons in the last shell 14 00:01:34,099 --> 00:01:41,700 he can do two things he can lose these seven electrons to become neon if you take 15 00:01:42,739 --> 00:01:49,620 these electrons from chlorine then it would be exactly like neon or he can obtain 16 00:01:49,620 --> 00:01:56,579 one extra electron from another atom and then become argon as you can imagine 17 00:01:57,700 --> 00:02:07,939 it's much easier for chlorine to accept to gain one extra electron than to lose seven of them 18 00:02:07,939 --> 00:02:16,500 so the general tendency of chlorine is to obtain one extra electron which is represented by its 19 00:02:16,500 --> 00:02:23,379 oxidation number negative one means that he wants to accept one electron and this tendency 20 00:02:24,180 --> 00:02:33,020 is the same for all halogens in the same group that than chlorine now let's see what happens to 21 00:02:33,020 --> 00:02:41,500 sodium for example sodium has one electron in the last shell and eight electrons in the previous one 22 00:02:41,500 --> 00:02:49,219 so if he wants to become a noble gas he can do again two things he can lose this electron and 23 00:02:49,219 --> 00:02:57,340 remain with the eight in the previous cell or he can accept seven electrons to complete the last 24 00:02:57,340 --> 00:03:04,400 cell as you can imagine again it's much easier to lose one electron than to obtain seven so the 25 00:03:04,400 --> 00:03:12,939 tendency of sodium is always to give this last electron and that's why he has 26 00:03:12,939 --> 00:03:18,560 positive one as an oxidation number and this is the tendency of all the first 27 00:03:18,560 --> 00:03:23,840 group in the predictable all of them wants to give this last electron that 28 00:03:23,840 --> 00:03:28,560 they have except for the hydrogen which is a exception that has oxidation 29 00:03:28,560 --> 00:03:35,719 numbers of positive one and negative one which we're going to explain now one 30 00:03:35,719 --> 00:03:41,840 last example. Let's see what happens to magnesium. Magnesium has two electrons in 31 00:03:41,840 --> 00:03:47,539 the last cell and eight electrons in the previous one. Again to become a noble 32 00:03:47,539 --> 00:03:52,879 gas he can lose these two electrons and remain with these eight in the last cell 33 00:03:52,879 --> 00:04:01,280 or he can obtain or accept six electrons from other atoms. It's again much easier 34 00:04:01,280 --> 00:04:09,759 to lose two electrons than to accept six so the tendency of magnesium always is to lose these two 35 00:04:09,759 --> 00:04:16,959 electrons in the last shell to become a noble gas and this is the same tendency as the as for all 36 00:04:16,959 --> 00:04:23,920 the elements in the second group they all want to lose these two electrons that have in the last 37 00:04:23,920 --> 00:04:33,939 shell. That's why they have all oxidation number of positive 2. Notice that there 38 00:04:33,939 --> 00:04:37,939 are some elements that don't have a clear tendency. For example we have 39 00:04:37,939 --> 00:04:46,980 spoken about hydrogen which has positive 1 and negative 1 as oxidation number. 40 00:04:46,980 --> 00:04:53,759 This means that hydrogen can lose the only electron that it has 41 00:04:53,759 --> 00:05:00,060 or he can accept one electron to have two electrons in the last shell because 42 00:05:00,060 --> 00:05:05,699 the closest noble gas to hydrogen is helium which has two electrons in the 43 00:05:05,699 --> 00:05:15,180 last shell so hydrogen depending on which it combines two it can lose the 44 00:05:15,180 --> 00:05:22,319 electron or accept one electron now let's try to understand what happens 45 00:05:22,319 --> 00:05:27,839 when two atoms of different elements combine. In this first video we're going to study elements 46 00:05:27,839 --> 00:05:33,759 with hydrogen called metallic hydrates or hidruro-metallicos in Spanish. They are the 47 00:05:33,759 --> 00:05:39,519 combination of hydrogen with a metal from the periodic table. Remember the metals in the 48 00:05:39,519 --> 00:05:48,160 periodic table are the ones to the left of this line. All metals in the periodic table have 49 00:05:48,160 --> 00:05:57,600 something in common they have positive oxidation numbers which means that they prefer to give 50 00:05:57,600 --> 00:06:03,439 electrons than to accept them okay so all of the metals of the project table wants to give 51 00:06:03,439 --> 00:06:12,410 electrons because of their positive oxidation numbers in metallic hydrates hydrogen uses the 52 00:06:12,410 --> 00:06:19,689 oxidation number of negative one always because he's combining with metals that always have 53 00:06:20,250 --> 00:06:29,769 positive oxidation numbers so if metals want to give electrons then hydrogen chooses to accept 54 00:06:29,769 --> 00:06:37,290 them the general rule to combine atoms is that electrons must not be free this is if an element 55 00:06:37,290 --> 00:06:42,329 wants to give one electron there must be another element to accept it. The sum of 56 00:06:42,329 --> 00:06:50,870 given and accepted electrons must be zero. Let's see an example. Imagine we 57 00:06:50,870 --> 00:07:01,800 want to combine hydrogen with lithium. We have learned that lithium wants to give 58 00:07:01,800 --> 00:07:08,879 one electron and that's why he has positive one as oxidation number. 59 00:07:08,879 --> 00:07:18,959 remember that hydrogen uses its negative oxidation number which means that 60 00:07:18,959 --> 00:07:24,939 hydrogen wants to accept one electron so if lithium wants to give one electron 61 00:07:24,939 --> 00:07:33,649 and hydrogen wants to accept it then that's it we have one 62 00:07:33,649 --> 00:07:41,050 electron one given electron and one accepted electron and we sum up these 63 00:07:41,050 --> 00:07:54,009 two electrons then it's equal zero and then we can write the formula for the 64 00:07:54,009 --> 00:07:59,550 combination of hydrogen lithium which is lithium hydride or either the lithium 65 00:07:59,550 --> 00:08:12,819 let's see another example now we want to combine hydrogen with beryllium for 66 00:08:12,819 --> 00:08:22,160 example from the oxidation numbers we know that beryllium wants to give to 67 00:08:22,160 --> 00:08:29,720 electrons is that what what the oxidation number of plus 2 means and we 68 00:08:29,720 --> 00:08:37,039 said that hydrogen we in metallic hydrates in idrurus metallicus always 69 00:08:37,039 --> 00:08:45,100 acts with negative 1 that's it that's it hydrogen always want to obtain or to 70 00:08:45,100 --> 00:08:52,559 accept one electron now we have a problem because we told that no electrons can be 71 00:08:52,559 --> 00:09:02,419 free so if a beryllium wants to give two electrons we cannot write beryllium and 72 00:09:02,419 --> 00:09:12,379 hydrogen like this because one accepted electron and two given electrons have 73 00:09:12,379 --> 00:09:21,879 assumed are assumed like a not equal to zero so this cannot be like this instead 74 00:09:21,879 --> 00:09:33,159 if beryllium needs to give two electrons but hydrogen only can accept one then we 75 00:09:33,159 --> 00:09:43,129 need two hydrogens and then one of the hydrogen accept one of the electron and 76 00:09:43,129 --> 00:09:54,830 the other hydrogen accept another electron so this hydrogen accept one the 77 00:09:54,830 --> 00:10:04,190 beryllium gives two and this hydrogen except one and they sum all zero so the formula for the 78 00:10:04,190 --> 00:10:12,110 compound with hydrogen beryllium must be beryllium hydrogen two because we need two hydrogens two 79 00:10:12,110 --> 00:10:18,029 atoms of hydrogen for each one of the atoms of beryllium because of beryllium wants to give 80 00:10:18,029 --> 00:10:24,509 two electrons and hydrogen can only accept one. So this is the formula for 81 00:10:24,509 --> 00:10:33,450 beryllium hydride or hydrurode beryllium. In our last example we're going to learn 82 00:10:33,450 --> 00:10:38,029 what happens when an element has more than one oxidation number. Let's try for 83 00:10:38,029 --> 00:10:47,149 example to combine hydrogen with iron. As you already know iron has two possible 84 00:10:47,149 --> 00:10:54,649 oxidation numbers plus two or plus three this means that iron wants to give 85 00:10:54,649 --> 00:11:05,750 electrons but he can give two electrons or it can give three electrons depending 86 00:11:05,750 --> 00:11:17,230 on the conditions so if iron wants to give two electrons then we need two 87 00:11:17,230 --> 00:11:24,269 hydrogens to accept these two electrons of course so one is for this 88 00:11:24,269 --> 00:11:32,429 hydrogen and this goes to this hydrogen and this way we have accepted 89 00:11:32,429 --> 00:11:41,529 an electron, two given electrons and one accepted which is a sum of zero and so 90 00:11:41,529 --> 00:11:50,210 we have a compound with two atoms of hydrogen for each atom of iron but we 91 00:11:50,210 --> 00:11:57,970 can have another possibility which is that iron gives three electrons so in 92 00:11:57,970 --> 00:12:09,549 this case we need three hydrogens three atoms of hydrogen to accept these three 93 00:12:09,549 --> 00:12:20,350 electrons and then three electrons plus one plus minus one and plus negative one 94 00:12:20,350 --> 00:12:30,250 then it's equal to zero so this compound is iron hydride three which is 95 00:12:30,250 --> 00:12:37,629 hydrido de hierro as well as this one but they are different compounds with 96 00:12:37,629 --> 00:12:43,730 different properties in nature we can found these two compounds of course they 97 00:12:43,730 --> 00:12:48,070 have different formula because they have different proportions of hydrogen and 98 00:12:48,070 --> 00:12:56,470 iron and this is all caused by the two possibilities of the oxidation numbers 99 00:12:56,470 --> 00:13:04,480 of iron which are plus two and plus three the last thing we're going to 100 00:13:04,480 --> 00:13:08,419 learn in this video is to write the symbols in a formula in the correct 101 00:13:08,419 --> 00:13:13,340 order. To write the formula for binary compound we compare the positions of 102 00:13:13,340 --> 00:13:17,899 both elements in this diagram. The leftmost element is written first and 103 00:13:17,899 --> 00:13:27,679 then the rightmost. For example, in the previous examples we wrote the 104 00:13:27,679 --> 00:13:37,879 combination of iron and hydrogen. We had two possibilities due to the two 105 00:13:37,879 --> 00:13:43,580 oxidation numbers of iron but in both of the cases in both the compounds that we 106 00:13:43,580 --> 00:13:53,179 got we wrote first the iron and then the hydrogen and not first the hydrogen and 107 00:13:53,179 --> 00:14:03,019 then the iron this is incorrect and this is incorrect why do we do this because 108 00:14:03,019 --> 00:14:10,419 when we combine iron with hydrogen in this table in this diagram we find iron 109 00:14:10,419 --> 00:14:17,980 to the left of hydrogen then we write first high iron and then hydrogen 110 00:14:17,980 --> 00:14:23,720 another example if we want to for example write the formula for water 111 00:14:23,720 --> 00:14:32,019 which is a combination of hydrogen and oxygen as we find hydrogen to the left 112 00:14:32,019 --> 00:14:40,840 of oxygen then we have to write first hydrogen and then oxygen and not oxygen 113 00:14:40,840 --> 00:14:47,059 and then hydrogen this is incorrect okay another example for example if we want 114 00:14:47,059 --> 00:14:52,860 to write the formula of ammonia ammonia co in Spanish which is a combination of 115 00:14:52,860 --> 00:15:00,399 nitrogen and hydrogen again we write first nitrogen which is at the left and 116 00:15:00,399 --> 00:15:07,480 then hydrogen with the corresponding number according to the proportions in 117 00:15:07,480 --> 00:15:13,120 which nitrogen and hydrogen combines this is correct and the other possibility to 118 00:15:13,120 --> 00:15:18,879 write first the nitrogen and then the nitrogen is incorrect okay this is the 119 00:15:18,879 --> 00:15:25,159 correct order in which we write symbols and we can apply this general rule to 120 00:15:25,159 --> 00:15:30,340 any combination of two elements in this diagram for example let's say we want to 121 00:15:30,340 --> 00:15:37,580 combine potassium with sulfur then if potassium is on the left we have to 122 00:15:37,580 --> 00:15:43,419 write first potassium and then sulfur and then the number corresponding to the 123 00:15:43,419 --> 00:15:50,019 proportions in this case to number two in potassium okay this is correct and 124 00:15:50,019 --> 00:15:56,500 the other possibility to write first sulfur and then potassium is incorrect