1 00:00:00,000 --> 00:00:05,840 Super job, you guys. 2 00:00:05,840 --> 00:00:09,440 Hey, did you know that NASA is working with students 3 00:00:09,440 --> 00:00:13,960 to develop new products and new experiments for space research? 4 00:00:13,960 --> 00:00:17,360 Dr. John Poiman, a professor of chemistry and biochemistry 5 00:00:17,360 --> 00:00:19,520 at the University of Southern Mississippi, 6 00:00:19,520 --> 00:00:23,040 has some cool applications for microgravity research, 7 00:00:23,040 --> 00:00:26,000 which students just like you can be working on someday. 8 00:00:26,000 --> 00:00:32,560 What is buoyancy induced convection? 9 00:00:32,560 --> 00:00:35,640 What is the relationship between density and volume? 10 00:00:35,640 --> 00:00:39,120 What is the trend in the density versus temperature graph? 11 00:00:39,120 --> 00:00:40,080 Hi. 12 00:00:40,080 --> 00:00:43,720 NASA's reduced gravity program began in 1959. 13 00:00:43,720 --> 00:00:47,600 But in the past five years, students from over 100 schools 14 00:00:47,600 --> 00:00:50,560 have performed experiments in a microgravity environment. 15 00:00:50,560 --> 00:00:53,880 Several of my students and I have flown on the KC-135, 16 00:00:53,920 --> 00:00:56,080 NASA's flying laboratory. 17 00:00:56,080 --> 00:00:59,320 It's science that's interesting, challenging, and fun. 18 00:00:59,320 --> 00:01:01,080 One experiment we are conducting involves 19 00:01:01,080 --> 00:01:04,720 making new space age materials by a really cool process 20 00:01:04,720 --> 00:01:07,080 called frontal polymerization. 21 00:01:07,080 --> 00:01:09,440 And the other involves studying how molecules attract 22 00:01:09,440 --> 00:01:12,120 each other in fluids that mix. 23 00:01:12,120 --> 00:01:14,320 Everything is made up of very, very small pieces 24 00:01:14,320 --> 00:01:16,440 of stuff called molecules. 25 00:01:16,440 --> 00:01:18,040 Molecules attract each other. 26 00:01:18,040 --> 00:01:19,600 How strongly they attract determines 27 00:01:19,600 --> 00:01:22,720 if the stuff is a liquid, solid, or a gas. 28 00:01:22,720 --> 00:01:24,560 Some materials mix completely. 29 00:01:24,560 --> 00:01:25,760 Others do not. 30 00:01:25,760 --> 00:01:27,880 Here's something you can try at home yourself. 31 00:01:27,880 --> 00:01:30,480 We have water here, which has food coloring in it, 32 00:01:30,480 --> 00:01:31,920 and syrup. 33 00:01:31,920 --> 00:01:38,080 And as I pour the syrup in and stir it up, 34 00:01:38,080 --> 00:01:42,560 it'll make one continuous liquid. 35 00:01:42,560 --> 00:01:45,040 But if I take something that's immiscible with water, 36 00:01:45,040 --> 00:01:48,120 like mineral oil, and pour it into the water with food 37 00:01:48,120 --> 00:01:53,560 coloring, and mix this solution up, 38 00:01:53,560 --> 00:01:56,640 it will separate into two layers with time. 39 00:01:56,640 --> 00:01:59,000 Water molecules attract each other more strongly 40 00:01:59,000 --> 00:02:01,320 than they attract oil molecules, and so the water 41 00:02:01,320 --> 00:02:02,520 stays separate. 42 00:02:02,520 --> 00:02:04,120 A monomer is a small molecule that 43 00:02:04,120 --> 00:02:06,680 can be made to form long chains of monomers connected 44 00:02:06,680 --> 00:02:09,080 end to end, called a polymer. 45 00:02:09,080 --> 00:02:11,720 It's sort of like boxcars hooked together to form a train. 46 00:02:11,720 --> 00:02:14,080 The mixing process is called convection. 47 00:02:14,080 --> 00:02:16,120 It's the term for liquid motion. 48 00:02:16,120 --> 00:02:18,440 There are two ways in which convection can spontaneously 49 00:02:18,440 --> 00:02:19,640 occur in a liquid. 50 00:02:19,640 --> 00:02:21,240 One is caused by gravity, and it's 51 00:02:21,240 --> 00:02:24,240 called buoyancy-induced convection. 52 00:02:24,240 --> 00:02:26,800 Differences between the densities of the liquids 53 00:02:26,800 --> 00:02:29,080 make the lighter fluid rise and separate 54 00:02:29,080 --> 00:02:30,240 from the heavier fluid. 55 00:02:30,240 --> 00:02:32,040 Another type of convection is called 56 00:02:32,040 --> 00:02:34,600 interfacial tension-induced convection. 57 00:02:34,600 --> 00:02:36,080 Interfacial what? 58 00:02:36,080 --> 00:02:38,280 Interfacial tension-induced convection. 59 00:02:38,280 --> 00:02:39,840 Let's split the term up. 60 00:02:39,840 --> 00:02:43,240 First, interfacial tension is like the surface tension, 61 00:02:43,240 --> 00:02:46,720 which holds up a water bug when it skitters across a pond. 62 00:02:46,720 --> 00:02:48,840 The surface is the result of the water molecules 63 00:02:48,840 --> 00:02:50,040 attracting each other. 64 00:02:50,040 --> 00:02:51,640 But heating a surface here on Earth 65 00:02:51,640 --> 00:02:54,240 causes buoyancy-induced convection. 66 00:02:54,240 --> 00:02:55,920 How can we study only the convection 67 00:02:55,920 --> 00:02:58,280 caused by interfacial effects alone? 68 00:02:58,280 --> 00:03:01,280 We need to eliminate gravity or its effects. 69 00:03:01,280 --> 00:03:04,080 We can never eliminate gravity, but by free-falling, 70 00:03:04,080 --> 00:03:08,120 we can create a system that acts as if there were no gravity. 71 00:03:08,120 --> 00:03:10,040 Performing experiments in weightlessness 72 00:03:10,040 --> 00:03:12,920 allows us to study phenomena we can't study on Earth 73 00:03:12,920 --> 00:03:15,800 and to answer questions we can't answer down here. 74 00:03:15,800 --> 00:03:18,200 By eliminating buoyancy-induced convection, 75 00:03:18,200 --> 00:03:20,480 we sometimes can create superior protein crystals 76 00:03:20,480 --> 00:03:23,800 in weightlessness that can help researchers design new drugs. 77 00:03:23,800 --> 00:03:25,840 Eliminating buoyancy-induced convection 78 00:03:25,840 --> 00:03:28,400 can also help us understand how to make better semiconductors 79 00:03:28,400 --> 00:03:31,560 here on Earth, like the ones used in your computer. 80 00:03:31,560 --> 00:03:34,240 We take a lesson from computer chip manufacturers 81 00:03:34,240 --> 00:03:36,640 who use light to make the circuit patterns. 82 00:03:36,640 --> 00:03:38,680 Microgravity research shows us that we 83 00:03:38,680 --> 00:03:41,120 can create patterns on fluids which would not 84 00:03:41,120 --> 00:03:43,760 be allowed on Earth, where buoyancy convection mixes 85 00:03:43,760 --> 00:03:45,600 up the patterns due to gravity. 86 00:03:45,600 --> 00:03:48,680 My students and I are studying how forces between molecules 87 00:03:48,680 --> 00:03:51,040 in fluids that mix can cause convection. 88 00:03:51,040 --> 00:03:52,840 We use light as an initiating agent 89 00:03:52,840 --> 00:03:55,280 to make the monomer turn into the polymer. 90 00:03:55,280 --> 00:03:58,320 By exposing the monomer to light with a specific pattern, 91 00:03:58,320 --> 00:04:00,360 we hope to observe how the monomer and polymer 92 00:04:00,360 --> 00:04:02,400 molecules pull on each other. 93 00:04:02,400 --> 00:04:04,320 For many minutes, we predict that the two fluids 94 00:04:04,320 --> 00:04:06,480 will act like oil on water. 95 00:04:06,480 --> 00:04:08,080 But in the long run, the molecules 96 00:04:08,080 --> 00:04:10,520 will diffuse into each other and make a single fluid. 97 00:04:10,520 --> 00:04:12,920 Why can't we do the experiment in the lab? 98 00:04:12,920 --> 00:04:14,400 Because buoyancy-driven convection 99 00:04:14,400 --> 00:04:15,680 will smear everything out. 100 00:04:15,680 --> 00:04:18,320 So there really is no way on Earth to do the experiment. 101 00:04:18,320 --> 00:04:21,760 We also study a process called frontal polymerization, 102 00:04:21,760 --> 00:04:23,320 in which plastics and foams can be 103 00:04:23,320 --> 00:04:25,080 made with a chemical reaction that 104 00:04:25,080 --> 00:04:27,360 spreads out like a liquid flame. 105 00:04:27,360 --> 00:04:29,120 Gases can be released by the hot reaction 106 00:04:29,120 --> 00:04:31,680 that makes bubbles, which can form the foam. 107 00:04:31,680 --> 00:04:34,800 Of course, bubbles float in a liquid because of gravity. 108 00:04:34,800 --> 00:04:36,360 But without the buoyant force, bubbles 109 00:04:36,360 --> 00:04:39,040 can become larger in a microgravity environment. 110 00:04:39,040 --> 00:04:41,200 How do you use math in your work? 111 00:04:41,200 --> 00:04:43,200 Math is essential to our work. 112 00:04:43,200 --> 00:04:46,000 For example, in order to predict how gravity will cause 113 00:04:46,000 --> 00:04:47,840 convection in our systems, we need 114 00:04:47,840 --> 00:04:50,160 to prepare graphs of the density of our materials 115 00:04:50,160 --> 00:04:51,840 as a function of temperature. 116 00:04:51,840 --> 00:04:54,960 We use a special instrument called a densitometer. 117 00:04:54,960 --> 00:04:56,920 But we have to know how to use the math to make 118 00:04:56,920 --> 00:04:58,680 sense of what it tells us. 119 00:04:58,680 --> 00:05:00,640 Let's look at some of the data from my lab. 120 00:05:00,640 --> 00:05:02,100 Here, we have plotted the densities 121 00:05:02,100 --> 00:05:04,360 of the monomer and the polymer on the y-axis 122 00:05:04,360 --> 00:05:06,400 and the temperature on the x-axis. 123 00:05:06,400 --> 00:05:08,680 First, notice that the density of the polymer 124 00:05:08,680 --> 00:05:11,200 is higher than the monomer. 125 00:05:11,200 --> 00:05:14,040 Next, we can draw straight lines through the points. 126 00:05:14,040 --> 00:05:15,840 The slope of each line is the ratio 127 00:05:15,840 --> 00:05:19,400 of the change in density to the change in temperature. 128 00:05:19,400 --> 00:05:23,440 The density of the polymer decreases 0.03 grams 129 00:05:23,440 --> 00:05:26,320 per cubic centimeters for a 50 degree centigrade 130 00:05:26,320 --> 00:05:28,960 increase in temperature. 131 00:05:28,960 --> 00:05:31,240 The density of the monomer also decreases, 132 00:05:31,240 --> 00:05:34,280 but it decreases 0.04 grams per cubic centimeter 133 00:05:34,280 --> 00:05:36,080 for the same temperature change. 134 00:05:36,080 --> 00:05:38,080 Remember that we said buoyancy-driven convection 135 00:05:38,080 --> 00:05:41,160 happens because of differences in density 136 00:05:41,160 --> 00:05:44,240 and that the less dense liquids will float to the top. 137 00:05:44,240 --> 00:05:46,280 Information from this graph tells us 138 00:05:46,280 --> 00:05:49,400 how the density changes when we heat the monomer and polymer. 139 00:05:49,400 --> 00:05:52,320 And so we can predict how much buoyancy-driven convection will 140 00:05:52,320 --> 00:05:55,080 occur during experiments on Earth. 141 00:05:55,080 --> 00:05:57,920 The graph also tells us how much the volume changes 142 00:05:57,920 --> 00:06:00,240 as we heat the liquids, essential information 143 00:06:00,240 --> 00:06:02,720 for designing our experiment on the International Space 144 00:06:02,720 --> 00:06:03,800 Station. 145 00:06:03,800 --> 00:06:06,560 As we go farther and farther from Earth into space, 146 00:06:06,560 --> 00:06:08,120 we're going to be required eventually 147 00:06:08,120 --> 00:06:10,200 to make our own materials in space. 148 00:06:10,200 --> 00:06:12,640 Foams are just one of the things we need to look at. 149 00:06:12,640 --> 00:06:15,200 Gaining an understanding of the opportunities in microgravity 150 00:06:15,200 --> 00:06:17,760 research today will be valuable knowledge 151 00:06:17,760 --> 00:06:20,640 for you, young researchers of tomorrow, 152 00:06:20,640 --> 00:06:24,080 when we are ready for our first manned flight to Mars.