1 00:00:02,220 --> 00:00:09,419 Hello guys, we're going to continue with a series of videos about how to name organic compounds 2 00:00:09,419 --> 00:00:22,399 following IUPERC rules. At the end of this video you should be able to identify a name correctly, 3 00:00:22,399 --> 00:00:31,519 alkyens and alkyens. So let's start. Alkyens are hydrocarbons with a double bone. 4 00:00:31,519 --> 00:00:43,520 To make the name of analkene, we need to use the root, which is related to the number of carbon atoms present in the molecule, and the ending "-ene". 5 00:00:43,520 --> 00:00:56,520 If we take the first one as an example, we can see C2H4. It has two carbon atoms, F, the ending "-ene", ethene. 6 00:00:56,520 --> 00:01:24,299 With three carbon atoms, it is CH2 double bond, CH, CH3. The root is propene, the ending in propene. However, when we reach to C4H8, there are two possible compounds, depending on where the double bond is placed. 7 00:01:24,299 --> 00:01:35,299 Then, we need to indicate the position of the double bond with the number, which is called locant. 8 00:01:35,299 --> 00:01:43,299 In the first case, the double bond is near the terminal carbon. 9 00:01:43,299 --> 00:01:51,299 So, put, because it has 4 carbon atoms, and 1 in. 10 00:01:51,299 --> 00:02:06,299 If we started numbering from the other end of the molecule, the double bone would be in 3. So, it is chosen the first option. 11 00:02:06,299 --> 00:02:23,300 In the second hydrocarbon, the double bond is placed in between. It doesn't matter from where we start numbering, because in both cases, the double bond would be in 2. 12 00:02:23,300 --> 00:02:37,719 Then, the name is root because it has four carbons, to, in. Remember to put hyphons between the root, the locant and the suffix. 13 00:02:39,919 --> 00:02:49,479 Let's do the next one, the following example. C5H10. It has five carbon atoms, so the root is pent. 14 00:02:49,479 --> 00:02:58,020 In the first molecule, the double bone is placed near the terminal carbon, so bent 1. 15 00:02:59,120 --> 00:03:10,099 In the second case, we need to start numbering by the end that assigns the lowest locant to the double bone. 16 00:03:10,099 --> 00:03:18,479 In this case, it's from left to right, then the name would be bent 2 in. 17 00:03:19,479 --> 00:03:28,090 When the compound has two double bones, it is a diene. 18 00:03:28,090 --> 00:03:32,669 They are named. Here we have two examples. 19 00:03:33,409 --> 00:03:39,849 In the first one, there are four carbon atoms, so the prefix is but. 20 00:03:40,530 --> 00:03:46,050 And then there are two double bones in one and three. 21 00:03:46,050 --> 00:03:52,449 The name is Buddha 1,3 Da-in. 22 00:03:53,330 --> 00:04:03,409 In the second case, there are two double bones, but we need to choose from which end to start numbering. 23 00:04:03,830 --> 00:04:12,389 If we go from left to right, the first double bone would be in 3. 24 00:04:12,389 --> 00:04:20,170 Whereas, if we start from right to left, the first double bond is found in 1. 25 00:04:21,170 --> 00:04:23,430 Then, let's take the second option. 26 00:04:23,949 --> 00:04:27,990 Hexa-1,3-diene. 27 00:04:29,990 --> 00:04:33,029 All kinds of hydrocarbons with a triple bond. 28 00:04:33,029 --> 00:04:40,449 They are named exactly in the same way as alkenes, but using the suffix "-ine". 29 00:04:40,449 --> 00:04:54,569 For example, the easiest is CH, triple bond, CH, F because it has two carbon atoms and the ending I, in time. 30 00:04:54,569 --> 00:04:58,149 It has a special name, acetylene. 31 00:05:01,240 --> 00:05:02,939 Let's do a couple of examples. 32 00:05:04,319 --> 00:05:11,079 In the first example, there are five carbon atoms, so the root is pent. 33 00:05:11,079 --> 00:05:19,399 The triple bone is placed in the first, in position 1, so pent, 1, iron. 34 00:05:19,399 --> 00:05:24,199 In the second case, the 6 carbon atoms, so hex. 35 00:05:25,459 --> 00:05:35,800 The double bone, if we start from numbering, from left to right, is in 2, hex, 2, iron. 36 00:05:35,800 --> 00:05:46,620 When there are two or three triple bonds in the molecule, the prefixes di-, tri- or even 37 00:05:46,620 --> 00:05:50,060 tetra- will be used. 38 00:05:50,060 --> 00:05:58,959 In the first example, there are five carbon atoms, so the root is penta and then if we 39 00:05:58,959 --> 00:06:07,339 start numbering from left to right. The triple bones would be in one and four. 40 00:06:07,339 --> 00:06:16,120 Penta, one, four. Di, iron. In the second case there are seven carbon atoms so 41 00:06:16,120 --> 00:06:25,180 hepta. It will start from left to right. The triple bones will be in one and 42 00:06:25,180 --> 00:06:33,579 in five however it will start numbering from right to left the first triple bone is in two 43 00:06:35,019 --> 00:06:45,420 then using the lowest possible lock hint rule that we will start from left to right the name is penta 44 00:06:45,420 --> 00:06:55,420 1,5-di-ion. In the last example, there are nine carbon atoms, so the prefix is Nona. 45 00:06:56,459 --> 00:07:09,420 Starting from left to right, the triple bonds are found in 1, 4 and 7. The name is Nona 1,4,5-tri-ion. 46 00:07:09,420 --> 00:07:18,180 Alkenines are acyclic hydrocarbons which contain both double and triple bonds. 47 00:07:18,180 --> 00:07:25,959 In this case the rules are a bit more complicated, firstly we need to identify the main chain 48 00:07:25,959 --> 00:07:33,250 which is the longest chain that contains all unsaturated bonds. 49 00:07:33,250 --> 00:07:39,129 Now the question arises from which end we need to start numbering. 50 00:07:39,129 --> 00:07:51,110 It's always going to start numbering by the end that assigns the lowest lock-end to the unsaturated bones, regardless whether they are double or triple bone. 51 00:07:53,079 --> 00:07:55,360 So, let's try to solve the first example. 52 00:07:55,360 --> 00:07:57,480 There are 7 carbon atoms. 53 00:07:58,339 --> 00:08:00,899 It will start numbering from left to right. 54 00:08:01,160 --> 00:08:04,199 The double bone is in 2 and the triple in 4. 55 00:08:04,920 --> 00:08:07,480 It will start numbering from right to left. 56 00:08:07,480 --> 00:08:29,800 The double bone is in five and the triple is in three. We're gonna choose from left to right because in this way the lowest locants are assigned. Helped because it has seven carbon atoms. Two in, five iron. 57 00:08:29,800 --> 00:08:39,120 Let's try to solve the next example. Here there are 6 carbon atoms. If we start numbering 58 00:08:39,120 --> 00:08:46,899 from left to right, the triple bone is in 1 and the double bone is in 4. However, if 59 00:08:46,899 --> 00:08:55,059 we start the other way round, the double bone is in 2 and the triple in 5. Then, from left 60 00:08:55,059 --> 00:09:09,700 to right is preferred because lowest locants are assigned to the unsaturated bones . 61 00:09:09,700 --> 00:09:17,899 In the following example, if we start numbering from left to right, the triple is in 1 and 62 00:09:17,899 --> 00:09:27,100 the double in 5. However, from right to left, the double is in 1 and the triple in 5. In 63 00:09:27,100 --> 00:09:34,700 case it is possible to choose and according to the rule we need to select the numbering scheme 64 00:09:34,700 --> 00:09:45,019 which assigns the lowest lock end to the double bone then from right to left hex one in five on 65 00:09:46,460 --> 00:09:51,740 finally in the last example the molecule has seven 66 00:09:51,740 --> 00:10:01,139 The double bone is in 1 and the triple bone is in 5. 67 00:10:01,139 --> 00:10:09,500 So hepta 1,5 diene 6 iron. 68 00:10:09,500 --> 00:10:13,539 Thanks a lot for watching this video, see you next time, bye.